It seems that there are a never ending number of processes for producing and storing hydrogen. This one, from Purdue University, stands out as one of the most promising. It potentially can create hydrogen on demand in a container small enough to be placed in a vehicle. It does produce byproducts that must be recycled, but there are standard, economical methods to do this. While referred to as a pollution-free energy source, that refers to the only to the process of producing hydrogen, some pollution would from the recycling process.
Researchers at Purdue University have further developed a technology that could represent a pollution-free energy source.
Aluminum is well known for a large negative free energy for the formation of its oxide. Hence, Al has the thermodynamic ability to split water. As such, were it not for its passivating oxide, Al would be a contender as a safe, economically viable material for energy storage, transport, and the generation of hydrogen.
The technology produces hydrogen by adding water to an alloy of aluminum and gallium. When water is added to the alloy, the aluminum splits water by attracting oxygen, liberating hydrogen in the process. The Purdue researchers are developing a method to create particles of the alloy that could be placed in a tank to react with water and produce hydrogen on demand.
The gallium is a critical component because it hinders the formation of an aluminum oxide skin normally created on aluminum's surface after bonding with oxygen, a process called oxidation. This skin usually acts as a barrier and prevents oxygen from reacting with aluminum. Reducing the skin's protective properties allows the reaction to continue until all of the aluminum is used to generate hydrogen, said Jerry Woodall, a distinguished professor of electrical and computer engineering at Purdue who invented the process.
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